1,3,4-THIADIAZOLE AND ITS DERIVATIVES: AN OVERVIEW ON CRYSTAL STRUCTURE AND TRIBOLOGY ACTIVITIES
Keywords:
1,3,4- thiadiazole, crystal, anti-corrosion, extreme pressure, tribologyAbstract
1,3,4-thiadiazole derivatives has been attracted great attention due to application in various areas. Synthesis and crystal structure is briefly investigated. Their application in high temperature and high pressure as anti-friction and antiwear, and improve the anti-wear and extreme pressure properties have been described. The effect of various 1,3,4-thiadiazole additives on the tribological properties of base oils is studied. This paper aims to present an overview of the role of 1,3,4-thiadiazole and its derivative in improving the tribological properties of base oils.
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J. Schatz, K. Gogic, and T. Benkert, “1,3,4-Thiadiazoles,” in Organic Chemistry 1, no. January, 2020, pp. 1–41.
S. T. Malinovski, G. G. Rusu, N. A. Barba, M. Z. Krimer, and J. Lipkowski, “Crystal Structure of 5-(2’-Aminophenyl)-2-Dimethylamino-1,3,4-Thiadiazole,” 2000. doi: 10.1038/105646a0.
P. Z. Hu, J. G. Wang, J. Liu, and B. T. Zhao, “Two novel crystal structures of 2-mercapto-1,3,4-thiadiazole complexes with mercury (II) chloride,” J. Chem. Crystallogr., vol. 40, no. 10, pp. 825–830, 2010, doi: 10.1007/s10870-010-9747-1.
P. Panini, T. P. Mohan, U. Gangwar, R. Sankolli, and D. Chopra, “Quantitative crystal structure analysis of 1,3,4-thiadiazole derivatives,” CrystEngComm, vol. 15, no. 22, pp. 4549–4564, 2013, doi: 10.1039/c3ce40278a.
N. Kerru, L. Gummidi, S. V. H. S. Bhaskaruni, S. N. Maddila, P. Singh, and S. B. Jonnalagadda, “A comparison between observed and DFT calculations on structure of 5-(4-chlorophenyl)-2-amino-1,3,4-thiadiazole,” Sci. Rep., vol. 9, no. 1, pp. 1–17, 2019, doi: 10.1038/s41598-019-55793-5.
A. Laachir et al., “Novel 1-D copper(II) coordination polymer based on 2,5-bis(pyridine-2-yl)-1,3,4-thiadiazole as bridging ligand: Synthesis, crystal structure, Hirshfeld surface analysis, spectroscopic characterizations and biological assessment,” J. Mol. Struct., vol. 1218, p. 128533, 2020, doi: 10.1016/j.molstruc.2020.128533.
L. Heidari, M. Ghassemzadeh, D. Fenske, O. Fuhr, M. Saeidifar, and F. Mohsenzadeh, “Unprecedented palladium(ii) complex containing dipodal 1,3,4-thiadiazole derivatives: Synthesis, structure, and biological and thermal investigations,” New J. Chem., vol. 44, no. 39, pp. 16769–16775, 2020, doi: 10.1039/d0nj02918a.
A. Dylong et al., “Crystal structure determination of 4‐[(Di‐p‐tolyl‐amino)‐ benzylidene]‐(5‐pyridin‐4‐yl‐[1,3,4]thiadiazol‐2‐yl)‐imine along with selected properties of imine in neutral and protonated form with camforosulphonic acid: Theoretical and experimental studies,” Materials (Basel)., vol. 14, no. 8, pp. 1–20, 2021, doi: 10.3390/ma14081952.
L. Cao, D. ‐P Wei, and R. Wang, “A study of the tribological properties of some 1,3,4‐thiadiazole type lubricant additives,” Lubr. Sci., vol. 7, no. 2, pp. 181–185, 1995, doi: 10.1002/ls.3010070207.
J. R. Xavier, S. Nanjundan, and N. Rajendran, “Electrochemical Adsorption Properties and Inhibition of Brass Corrosion in Natural Seawater by Thiadiazole Derivatives : Experimental and Theoretical Investigation,” Ind. Eng. Chem. Res., vol. 51, pp. 30–43, 2012.
Q. H. Zhang, B. S. Hou, and G. A. Zhang, “Inhibitive and adsorption behavior of thiadiazole derivatives on carbon steel corrosion in CO2-saturated oilfield produced water: Effect of substituent group on efficiency,” J. Colloid Interface Sci., vol. 572, pp. 91–106, 2020, doi: 10.1016/j.jcis.2020.03.065.
H. Mi, W. Wang, Y. Liu, and T. Wang, “Theoretical evaluation of corrosion inhibition performance of six thiadiazole derivatives,” J. Theor. Comput. Chem., vol. 19, no. 2, 2020, doi: 10.1142/S0219633620500108.
I. K. Jassim, I. Y. Mohammed, and S. Salman, “Synthesis of anti-corrosion polymers from thiadiazole,” IOP Conf. Ser. Mater. Sci. Eng., vol. 736, no. 4, 2020, doi: 10.1088/1757-899X/736/4/042042.
B. Chugh et al., “Comparative Investigation of Corrosion-Mitigating Behavior of Thiadiazole-Derived Bis-Schiff Bases for Mild Steel in Acid Medium: Experimental, Theoretical, and Surface Study,” ACS Omega, vol. 5, no. 23, pp. 13503–13520, 2020, doi: 10.1021/acsomega.9b04274.
A. Alamiery, J. M. Ali, and W. N. R. Isahak, “Experimental studies on the corrosion inhibition of mild steel by 1-(phenylamino-1,3,4-thiadiazol-5-yl)-3-phenyl-3-oxopropan complemented with DFT Modeling,” Koroze a Ochr. Mater., vol. 66, no. 1, pp. 7–15, 2022, doi: 10.2478/kom-2022-0002.
A. Ma, M. Gu, J. Yao, and R. “Ray” Zhang, “Synergistic Combination of Dimercapto Thiadiazole Derivatives with Organo-Moly as EP Additives in Greases,” The European Lubricants Industry, no. 97, pp. 32–37, Apr. 2015.
Y. Hu, C. Li, X. Wang, Y. Yang, and H. Zhu, “1,3,4-Thiadiazole: Synthesis, Reactions, and Applications in Medicinal, Agricultural, and Materials Chemistry,” Chem. Rev., vol. 114, pp. 5572–5610, 2014.
H. Chen, J. Yan, T. Ren, Y. Zhao, and L. Zheng, “Tribological behavior of some long-chain dimercaptothiadiazole derivatives as multifunctional lubricant additives in vegetable oil and investigation of their tribochemistry using XANES,” Tribol. Lett., vol. 45, no. 3, pp. 465–476, 2012, doi: 10.1007/s11249-011-9910-7.
J. Wang, J. Wang, C. Li, G. Zhao, and X. Wang, “A study of 2,5-dimercapto-1,3,4-thiadiazole derivatives as multifunctional additives in water-based hydraulic fluid,” Ind. Lubr. Tribol., vol. 66, no. 3, pp. 402–410, 2014, doi: 10.1108/ilt-11-2011-0094.
Q. Shen, H. Chen, and L. Li, “Synthesis and tribological behavior of 1,3,4-thiadiazole Schiff base derivatives as multifunctional lubricant additives,” China Pet. Process. Petrochemical Technol., vol. 19, no. 2, pp. 80–88, 2017.
J. Tan, Y. Wang, M. Liu, and J. Liu, “Study of the effect of overbased calcium or magnesium sulfonate combinated with thiazole derivatives in rapeseed oil on tribological properties,” Ind. Lubr. Tribol., vol. 70, no. 7, pp. 1258–1267, 2018, doi: 10.1108/ILT-10-2017-0314.
P. Zu, Y. Zhang, Y. Li, S. Zhang, J. Li, and L. Hu, “Structure design and performance investigation of 2-mercapto-5-methyl thiadiazole based ionic liquids as lubricants and corrosion inhibitors,” Tribol. Int., vol. 173, no. June, pp. 1–12, 2022, doi: 10.1016/j.triboint.2022.107682.